In this study, thermal stability of fibers obtained from recycled MDF was investigated and compared with virgin fibers by using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Two different methods, including electrical heating and hydrothermal treatment, were used for recycling the MDF wastes. Electrical heating method was performed at two different times (2 and 4 min) and hydrothermal method was done at three different temperatures (105, 125 and 150 °C). Chemical structure of wood fibers was also studied. TGA and DSC analysis showed higher weight loss of recycled fibers as compared to virgin fibers in a similar degradation region, which means that thermal stability of recycled fibers is lower than virgin fibers. In fact, thermal behavior of recycled fibers was medium between wood and UF resin. DSC analysis showed two exotherms at around 340 and 475 °C. The transition at around 340 °C in fibers thermogram was considered to be due to polysaccharides thermal deterioration and the exotherm at 475 °C was related to lignin carbohydrate complex deterioration. The results of chemical structure analysis showed that lignin and hemicellulose content of recycled fibers was significantly lower than that of virgin fibers, which resulted in decreased thermal stability.; U ovom je istraživanju proučavana toplinska stabilnost vlakana dobivenih od recikliranih MDF ploča te je uz pomoć termogravimetrijske analize (TGA) i diferencijalne skenirajuće kalorimetrije (DSC) uspoređena s izvornim vlaknima. Za recikliranje otpadnih MDF ploča primijenjene su dvije različite metode – električno zagrijavanje i hidrotermička obrada. Metoda električnog zagrijavanja provedena je tijekom dva različita vremenska trajanja (2 i 4 min), a hidrotermička metoda provedena je pri tri različite temperature (105, 125 i 150 °C). Proučavana je i kemijska struktura drvnih vlakana. Analize TGA i DSC pokazale su veći gubitak mase recikliranih vlakana u usporedbi s izvornim vlaknima u sličnoj fazi razgradnje, što znači da je toplinska stabilnost recikliranih vlakana niža od toplinske stabilnosti izvornih vlakana. Zapravo, toplinsko ponašanje recikliranih vlakana nalazi se između drva i UF smole. DSC analizom dobivena su dva egzotermna pika na oko 340 i 475 °C. Prijelaz na oko 340 °C u termogramu pripisuje se propadanju polisaharida, a egzotermna reakcija na 475 °C posljedica je propadanja spojeva ugljikohidrata i lignina. Rezultati analize kemijske strukture pokazali su da je sadržaj lignina i hemiceluloze u recikliranim vlaknima znatno manji od njegova sadržaja u izvornim vlaknima, što je rezultiralo smanjenjem toplinske stabilnosti.